【英文标准名称】:StandardPracticeforPreparationofWaterSamplesUsingReductivePrecipitationPreconcentrationTechniqueforICP-MSAnalysisofTraceMetals
【原文标准名称】:用微量金属的ICPMS分析法使用快速还原浓缩技术对水样品制备的标准实施规程
【标准号】:ASTMD6800-2002(2007)e1
【标准状态】:现行
【国别】:
【发布日期】:2002
【实施或试行日期】:
【发布单位】:美国材料与试验协会(US-ASTM)
【起草单位】:D19.05
【标准类型】:(Practice)
【标准水平】:()
【中文主题词】:
【英文主题词】:ambient;brackish;brine;elements;estuarine;inductivelycoupledplasma-massspectrometry;pre-concentration;seawater;water
【摘要】:Ambientmarinewatersgenerallycontainverylowconcentrationsoftoxicmetalsthatrequiresensitiveanalyticalmethods,suchasICP-MS,todetectandmeasurethemetalrsquo;concentrations.Duetothehighdissolvedsaltconcentrationspresentinseawater,samplepretreatmentisrequiredtoremovesignalsuppressionandsignificantpolyatomicinterferencesduetothematrixbothofwhichcompromisedetectionlimits.1.1Toxicelementsmaybepresentinambientwatersandmayenterthefoodchainviauptakebyplantsandanimals;theactualconcentrationsoftoxicmetalsareusuallysub-ng/mL.TheU.S.EPAhaspublisheditsWaterQualityStandardsintheU.S.FederalRegister40CFR131.36,Minimumrequirementsforwaterqualitystandardssubmission,Ch.I(7-1-00Edition),seeAnnex,.TheU.S.EPAhasalsodevelopedMethod1640tomeettheserequirements,seeAnnex,.1.2InductivelyCoupledPlasmaMassSpectroscopy(ICP-MS)isatechniquewithsufficientsensitivitytoroutinelymeasuretoxicelementsinambientwaters,bothfreshandsaline(TestMethodD5673).HoweversalineandhardwatermatricesposeanalyticalchallengesfordirectmultielementanalysisbyICP-MSattherequiredsub-ng/mLlevels.1.3ThisstandardpracticedescribesamethodusedtopreparewatersamplesforsubsequentmultielementanalysisusingICP-MS.Thepracticeisapplicabletoseawaterandfreshwatermatrices,whichmaybefilteredordigested.SamplespreparedbythismethodhavebeenanalyzedbyICP-MSfortheelementslistedinAnnex,TableA1.3).Thisstandarddoesnotpurporttoaddressallofthesafetyconcerns,ifany,associatedwithitsuse.Itistheresponsibilityoftheuserofthisstandardtoestablishappropriatesafetyandhealthpracticesanddeterminetheapplicabilityofregulatorylimitationspriortouse.
【中国标准分类号】:G13
【国际标准分类号】:13_060_45
【页数】:8P.;A4
【正文语种】: